There are several airlines that operate frequent flights from Milan (MXP) to Brasilia (BSB) including

• LATAM Airlines Group with 9 flights a week
• LATAM Airlines Brasil with 7 flights a week
• TAP Portugal with 5 flights a week
• Alitalia with 4 flights a week
• Azul Brazilian Airlines with 3 flights a week

The earliest flight leaves Malpensa Intl. Airport at 06:30 and arrives at Brasilia Intl. President Juscelino Kubitschek Airport at 10:20. The last flight of the day departs Milan at 22:10 and arrives at Brasilia at 22:10.

The flight distance from Milan to Brasilia is about 9546 km, the shortest flight is 13 hours 55 minutes with TAP Portugal.

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